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Date of Issue : Oct 1998 1. IDENTIFICATION
General Product Name : TRICHLOROISOCYANURIC ACID, DRY Other Names : TRICLOROISOCYANURIC ACID 1,3,5-TRICHLORO-s-TRIAZINE-2,4,6-TRIONE UN No. : 2468 Dangerous Goods Class : 5.1 Subsidiary Risk : None Allocated Hazchem Code : 2WE Pack Group : II EPG : 31 Poisons Schedule : 5 Uses : Active ingredient in household dry bleaches, dishwashing compounds, scouring powders, detergent-sanitisers, commercial laundry bleaches, swimming pool disinfectant, bactericide, algicide, bleach and deodorant.
1.1 Physical Description / Properties
Appearance : White crystalline powder with odour of chlorine. Formula : OCNClCONClCONCl Boiling Point : N/A deg C Melting Point : 225 deg C Vapour Pressure : N/A Specific Gravity : N/A (water = 1) Flash Point : Test Unknown 225 pH : approx 3 () Solubility in water : 12 g/l (25 deg C) Flammability Limits (as percentage volume in air) Lower Explosion Limit : N/A Upper Explosion Limit : N/A 1.2 Other Properties
No data available 1.3 Ingredients
2. HEALTH HAZARD INFORMATION
2.1 Health Effects - Acute Swallowed
The toxicological properties of this material have not been investigated. Eye
The toxicological properties of this material have not been investigated. Use appropriate procedures to prevent opportunities for direct contact with eyes. Skin
The toxicological properties of this material have not been investigated. Use appropriate procedures to prevent opportunities for direct contact with skin. Inhaled
The toxicological properties of this material have not been investigated. Use appropriate procedures to prevent inhalation. 2.2 Health Effects - Chronic
No data available
2.3 First Aid
Swallowed
If victim is conscious and alert, aloow them to rinse mouth then drink 2-4 cupfuls of water. DO NOT induce vomiting. Seek medical aid immediately.
Eye
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Seek medical attention immediately.
Skin
Wash affected areas thoroughly with soap and water for at least 15 minutes while removing contaminated clothing and shoes. If effects persist seek medical aid.
Inhaled
Seek medical attention immediately. Remove from exposure to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
First Aid Facilities
Ensure an eye bath and safety shower are available and ready for use.
2.5 Advice to Doctor
Treat symptomatically based on judgement of doctor and individual reactions of patient.
2.6 Toxicity Data
Oral LD50 = 406 mg/kg (Rat) Dermal LD50 = not available Inhalation LC50 = not available Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP or OSHA.
3. PRECAUTIONS FOR USE
3.1 Exposure Standards
An exposure standard has not been established for this product by Worksafe .
3.2 Engineering Controls
Ensure adequate ventilation to maintain exposure levels below applicable workplace standards, including the use of general or local exhaust ventilation, process enclosure or other engineering controls.
3.3 Personal Protection
Wear chemical goggles, safety glasses if splashing is possible. Wear appropriate protective gloves and clothing to prevent skin exposure. Wear breathing protection appropriate to airborne concentrations. Wash hands and face thoroughly after handling and before work breaks, eating, drinking, smoking and using toilet facilities.
3.4 Flammability
Material is an oxidiser which supports combustion. SAFE HANDLING INFORMATION
4.1 Storage / Transport
Avoid contact with clothing and other combustible materials. Do not store near combustible materials or in corrosives storage areas. Store in a cool, dry area away from heat and direct sunlight.
4.2 Packaging / Labelling UN No. 2468 Class 5.1 Sub Risk None Allocated Hazchem Code 2WE Pack Group II EPG No. 31 Shipping Name TRICHLOROISOCYANURIC ACID, DRY Hazard HARMFUL
Risk Phrases R8 Contact with combustible material may cause fire. R22 Harmful if swallowed. R31 Contact with acids liberates toxic gas. R36/37 Irritating to eyes and respiratory system.
Safety Phrases S8 Keep container dry. S26 In case of contact with eyes, rinse immediately with plenty of water and contact a doctor or . S41 In case of fire and/or explosion, do not breathe fumes.
4.3 Spills and Disposal
Spills
Clean-up personnel should wear full protective clothing including breathing apparatus in dusty conditions. Prevent material from entering drains, water courses and sewers.
Clean up spills immediately. Sweep up, then place in suitable containers for disposal.
Disposal
Dispose of in accordance with all Local, State and Federal regulations at an approved waste disposal facility.
4.4 FIRE AND EXPLOSION HAZARD Fire / Explosion
Material is stable under normal conditions of temperature and pressure. Incompatible with strong reducing agents, strong bases, moist air or water. Hazardous decomposition products include hydrogen chloride, nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases. Hazardous polymerisation has not been reported. On contact with nitrogen compounds, nitrogen trichloride fumes can be formed, which are very explosive. Reacts violently with calcium hypochlorite.
Extinguishing Media
Fire-fighters should wear full protective clothing including self-contained breathing apparatus. Use water, dry chemical, chemical foam or alcohol- resistant foam type extinguishers. Use equipment/media appropriate to surrounding fire conditions. 5 OTHER INFORMATION
Other Information
No data available
5.1 Contact Points
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The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use.
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